Caluanie 1L – Muelear Oxidize

HAZARDS IDENTIFICATION
Clear, colorless solution with caustic odor.
R35 – causes severe burns.
R26 – very toxic for inhalation
S1/2, S9, S16, S30, S28, S36/37, S45
Routes of Entry: Skin, eyes, inhalation and ingestion
3. FIRST AID INFORMATION
Inhalation of mists can cause corrosive action on mucous membranes, symptoms
include burning, chocking, coughing, wheezing, laryngitis, shortness of breath,
headache or nausea. Move casualty to fresh air and keep at rest. Get medical
attention if symptoms persist.
Inhalation:
Eyes: Contact rapidly causes server damage, symptoms include eye burns, watering eyes,
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Permanent damage to cornea may result. In case of eye contact, rinse with plenty of
Water and seek medical attention immediately.
Skin: Severe and rapid corrosion from contact. Extent of damage depends on duration of
contact. Symptoms include burning, itching, redness, inflammation and/or swelling of
exposed tissues. Harmful if absorbed through skin. Immediately flush with plenty of
water for at least 15 minutes while removing contaminated clothing and wash using
soap. Get medical attention immediately.
4. FIRE-FIGHTING MEASURES
FLAMMABLE PROPERTIES:
Flash Point: Not Flammable
Autoignition Temperature: Not Applicable
Upper Flame Limit (volume % in air): Not Applicable
Lower Flame Limit (volume % in air): Not Applicable
Extinguish Media: Product is not flammable. Use appropriate media for adjacent fire.
Special fire and explosion hazard: Wear self-contained, approved breathing apparatus and full
Protective clothing, including eye protection and boots.
Hazardous combustion products: Emits toxic fumes under fire conditions.
Unusual fire and explosion hazards: Material can react with metals to produce flammable
hydrogen gas.
5. ACCIDENTAL RELEASE MEASURES
Personal precautions: See section 8 for recommendations on the use of personal protective
equipment.
Environmental precautions: Cleanup personal need personal protection from inhalation and
skin/eye contact. Evacuate and ventilate the area. Prevent spillage from
entering drains. Cautiously add water to spill, taking care to avoid
splashing and spattering. Neutralize diluted spill with soda ash or lime.
Absorb neutralized spill with inert absorbent material, then place in a
suitable container for disposal. Clean surfaces thoroughly with water to
remove residual contamination. Any release to the environment may be
subjected to federal/national or local reporting requirements. Dispose of
all waste or cleanup material in accordance with local regulations.
containers, even when empty, will retain residue and vapors.
6. HANDLINE AND STORAGE
Normal handling: See section 8 for recommendations on the use of personal protective
equipment. Use with adequate ventilation. Wash thoroughly after using. Keep
container closed when not in use.
Storage: store in cool, dry well-ventilated area. Keep away from incompatible materials
(use section 10 for incompatibilities) Drains for storage or use areas for this
material should have retention basins for pH adjustment and dilution of pills.
7. EXPOSURE CONTROLS/PERSONAL PROTECTION
Ventilation: Provide local exhaust, preferably mechanical.
Respiratory protection: If necessary use an approved respirator with acid vapor cartridges.
Eye protection: Wear chemical safety glasses with a face shield for splash protection.
Skin and body protection: Wear neoprene or rubber gloves, apron and other protective
clothing appropriate to the risk of exposure.
Other Recommendations: Provide eyewash station, quick-drench showers and washing facilities
accessible to areas of use and handling. Have supplies and equipment for
neutralization and running water available.
8. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Clear , colorless liquid
Physical State: Liquid
Odor: Pungent odor, similar to the smell of acetic acid
Density: 1.86g /cm3
Boiling point: 31 – 3F (13 – 25 °C)
Solubility in Water: Insoluble
Vapor Pressure: ASTM D323
Coefficient of Water/Oil Distribution: Not Determined
Flash Point: 22 F (28° C) Tag Open Cup: 22 F (28 °C) Tag Open cup
Pour point: -63 C ( -81.4 F ) D-97
Specific Gravity: 0.8 – 0.32 @ 30 F
PH: Not Applicable
Vapor Density: Greater than 1
VOC: 412 grams/liter (49.5%)
Flammable Limits (Solvent Portion): LEL: 0.6% UEL:8.0%
Kinematic Viscosity: 2.97-2.96cSt @ 100 F
9. STABILITY AND REACTIVITY
Stability: Stable
Conditions to avoid: uncontrolled addition of oxidants.
Incompatibility: bases, organic materials, metals, carbides, cyanides, chlorates’, nitrates, picrates,
permanganate, peroxides, zinc ioddide, azides, perchlorates, phosphorus.
Hazardous decomposition prod: Carbon oxides.
Hazardous polymerization: Will not occur.
10. TOXICOLOGICAL INFORMATION
Acute Effects: See section 4 for symptoms of exposure and effects. Likely routes of exposure are
skin, eyes and inhalation.
Target organs: kidney, liver, mucous membranes, respiratory system, skin, eyes and
cardiovascular system.
Acute Toxicity Data: Lowest published lethal doses (LD/LCL)
LDL (Man) Oral: 2857 ug/kg
LCL (Human) – Route: Inhalation : Dose:1280 ppm/30M
LCL (Rabbit) – Route: inhalation, Dose 4400
ppm/30M LD50 (oral,rat) , 600 mg/kg
LC50 (rat): 3125 (1hour)
Chronic Effects: May affect liver, bleeding of nose and gums, nasal and oral mucosal ulceration,
conjunctivitis, yellowing of teeth and erosion of tooth enamel, dermatitis.
Teratogenicity: Not Available
Mutagenicity: Not Available
Embryotoxicity: Not Available
Synergistic Products/Effects: Not Available
11. ECOLOGICAL INFORMATION
Ecotoxicity (aquatic and terrestrial): LD50 @ pH of e3 – 3.6
LC80 (72 Hours): 56 mg/L (Daphnia Magna )
Persistence and Degradability: Not Available
Bio accumulative Potential: Not Available
Mobility in soil: Not Available
Other Adverse effects: Not Available
12. DISPOSAL CONSIDERATIONS
RCRA: Hazardous waste? Yes
RCRA ID number: DOO2
Waste Residues: Carefully dilute with water, neutralize per spill procedures in section 6.
Neutralized material may be flushed to sewer (REGULATIONS PERMITING) or disposed
of through a licensed contractor. Users should review their operations in terms of the
applicable federal /nation or local regulations and consult with appropriate regulatory
agencies before discharging or disposing of waste material.
Product containers: Containers , if thoroughly cleaned, preferably by rising three times and handling
the rinse water as waste residues, may be disposed of or recycled as nonhazardous waste. Users should review their operations in terms of the
applicable federal /nation or local regulations and consult with appropriate regulatory
agencies before discharging or disposing of waste material.
The information offered in section 13 is for the product as shipped, Use and/or alterations to
the product may significantly change the characteristics of the materials and alter the waste
classification and proper disposal methods.
CALUANIE Muelear oxidize, Material: Isocyanic acid A-B consist of modulators and activators:
1. HN02: 2 HNO3: 3, HBP: 4 H2EP2OF: 5, H, 6 HMNO4: 7. (HPOS) n: 8 (H2SiCs) m:
9. H4SiO: 10. H2SO
Transportation, storage and precautions: Store in a cool place in it’s original sealed packaging away
From fire at temperatures from -5C to +25C
Shelf life: No expiration date.
The material is intended for dissolving and burning out metal oxides. Doesn’t burn hands.
Note: This product is intended for civilian use.
13. TRANSPORTATION INFORMATION
DOT: UN1760,7,pg. II
TDG: UN1760,7,pg. II
PIN: Not Available
IDMG: UN1760,7,pg. II
Marine Pollution: No
14. REGULATORY INFORMATION
To avoid to humans and the environment, the operating instructions must
observed.